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・ Nickelus F
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Nickel(II) chloride
・ Nickel(II) fluoride
・ Nickel(II) hydroxide
・ Nickel(II) iodide
・ Nickel(II) nitrate
・ Nickel(II) nitrite
・ Nickel(II) oxide
・ Nickel(II) sulfate
・ Nickel(II) titanate
・ Nickel(III) oxide
・ Nickel-62
・ Nickel-dependent hydrogenase
・ Nickel-O-Zone
・ Nickel-transporting ATPase
・ Nickelback


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Nickel(II) chloride : ウィキペディア英語版
Nickel(II) chloride

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Nickel(II) chloride (or just nickel chloride), is the chemical compound NiCl2. The anhydrous salt is yellow, but the more familiar hydrate NiCl2·6H2O is green. In general nickel(II) chloride, in various forms, is the most important source of nickel for chemical synthesis. The nickel chlorides are deliquescent, absorbing moisture from the air to form a solution. Nickel salts are carcinogenic.
==Production and syntheses==
The largest scale production of nickel chloride involves the extraction with hydrochloric acid of nickel matte and residues obtained from roasting refining nickel-containing ores.
NiCl2·6H2O is rarely prepared in the laboratory because it is inexpensive and has a long shelf-life. Heating the hexahydrate in the range 66-133.°C gives the yellowish dihydrate, NiCl2·2H2O.〔Laird G. L. Ward "Anhydrous Nickel (II) Halides and their Tetrakis(Ethanol) and 1,2-Dimethoxyethane Complexes Inorganic Syntheses, 1972 Volume 13, pages 154–164. 〕 The hydrates convert to the anhydrous form upon heating in thionyl chloride or by heating under a stream of HCl gas. Simply heating the hydrates does not afford the anhydrous dichloride.
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The dehydration is accompanied by a color change from green to yellow.
In case one needs a pure compound without presence of cobalt, nickel chloride can be obtained cautiously heating hexammine nickel chloride:
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